The cache files are C:\Program Files\PokerAce Hud\Data\Temp\DBCachexxx.* so you could see if they are increasing in size.
Do you have logging enabled?
If so, attach PAHud.log to a
Support ticket and we'll see any problems are reported - I don't think the progress of the cache is written to it, though.
I'll ask whether there's anything else you can look at, but for a big DB like that it will take a while so I would leave it running for now.